The Terrorist's Cookbook Written BY: UNKNOWN AUTHOR (*)(*)(*)(*)(*)(*)(*)(*)(*)(*)(*)(*)(*)(*)(*) 3.0 EXPLOSIVE RECIPES Once again, persons reading this material MUST NEVER ATTEMPT TO PRODUCE ANY OF THE EXPLOSIVES DESCRIBED HEREIN. IT IS ILLEGAL AND EXTREMELY DANGEROUS TO ATTEMPT TO DO SO. LOSS OF LIFE AND/OR LIMB COULD EASILY OCCUR AS A RESULT OF ATTEMPTING TO PRODUCE EXPLOSIVE MATERIALS. These recipes are theoretically correct, meaning that an individual could conceivably produce the materials described. The methods here are usually scaled-down industrial procedures. 3.01 EXPLOSIVE THEORY An explosive is any material that, when ignited by heat or shock, undergoes rapid decomposition or oxidation. This process releases energy that is stored in the material in the form of heat and light, or by breaking down into gaseous compounds that occupy a much larger volume that the original piece of material. Because this expansion is very rapid, large volumes of air are displaced by the expanding gasses. This expansion occurs at a speed greater than the speed of sound, and so a sonic boom occurs. This explains the mechanics behind an explosion. Explosives occur in several forms: high-order explosives which detonate, low order explosives, which burn, and primers, which may do both. High order explosives detonate. A detonation occurs only in a high order explosive. Detonations are usually incurred by a shockwave that passes through a block of the high explosive material. The shockwave breaks apart the molecular bonds between the atoms of the substance, at a rate approximately equal to the speed of sound traveling through that material. In a high explosive, the fuel and oxodizer are chemically bonded, and the shockwave breaks apart these bonds, and re-combines the two materials to produce mostly gasses. T.N.T., ammonium nitrate, and R.D.X. are examples of high order explosives. Low order explosives do not detonate; they burn, or undergo oxidation. when heated, the fuel(s) and oxodizer(s) combine to produce heat, light, and gaseous products. Some low order materials burn at about the same speed under pressure as they do in the open, such as blackpowder. Others, such as gunpowder, which is correctly called nitrocellulose, burn much faster and hotter when they are in a confined space, such as the barrel of a firearm; they usually burn much slower than blackpowder when they are ignited in unpressurized conditions. Black powder, nitrocellulose, and flash powder are good examples of low order explosives. Primers are peculiarities to the explosive field. Some of them, such as mercury filminate, will function as a low or high order explosive. They are usually more sensitive to friction, heat, or shock, than the high or low explosives. Most primers perform like a high order explosive, except that they are much more sensitive. Still others merely burn, but when they are confined, they burn at a great rate and with a large expansion of gasses and a shockwave. Primers are usually used in a small amount to initiate, or cause to decompose, a high order explosive, as in an artillery shell. But, they are also frequently used to ignite a low order explosive; the gunpowder in a bullet is ignited by the detonation of its primer. 3.1 IMPACT EXPLOSIVES Impact explosives are often used as primers. Of the ones discussed here, only mercury fulminate and nitroglycerine are real explosives; Ammonium triiodide crystals decompose upon impact, but they release little heat and no light. Impact explosives are always treated with the greatest care, and even the stupidest anarchist never stores them near any high or low explosives. 3.11 AMMONIUM TRIIODIDE CRYSTALS Ammonium triiodide crystals are foul-smelling purple colored crystals that decompose under the slightest amount of heat, friction, or shock, if they are made with the purest ammonia (ammonium hydroxide) and iodine. Such crystals are said to detonate when a fly lands on them, or when an ant walks across them. Household ammonia, however, has enough impurities, such as soaps and abrasive agents, so that the crystals will detonate when thrown,crushed, or heated. Upon detonation, a loud report is heard, and a cloud of purple iodine gas appears about the detonation site. Whatever the unfortunate surface that the crystal was detonated upon will usually be ruined, as some of the iodine in the crystal is thrown about in a solid form, and iodine is corrosive. It leaves nasty, ugly, permanent brownish-purple stains on whatever it contacts. Iodine gas is also bad news, since it can damage lungs, and it settles to the ground and stains things there also. Touching iodine leaves brown stains on the skin that last for about a week, unless they are immediately and vigorously washed off. While such a compound would have little use to a serious terrorist, a vandal could utilize them in damaging property. Or, a terrorist could throw several of them into a crowd as a distraction, an action which would possibly injure a few people, but frighten almost anyone, since a small crystal that not be seen when thrown produces a rather loud explosion. Ammonium triiodide crystals could be produced in the following manner: Materials Equipment _________ _________ iodine crystals funnel and filter paper paper towels clear ammonia (ammonium hydroxide, two throw-away glass jars for the suicidal) 1) Place about two teaspoons of iodine into one of the glass jars. The jars must both be throw away because they will never be clean again. 2) Add enough ammonia to completely cover the iodine. 3) Place the funnel into the other jar, and put the filter paper in the funnel. The technique for putting filter paper in a funnel is taught in every basic chemistry lab class: fold the circular paper in half, so that a semi-circle is formed. Then, fold it in half again to form a triangle with one curved side. Pull one thickness of paper out to form a cone, and place the cone into the funnel. 4) After allowing the iodine to soak in the ammonia for a while, pour the solution into the paper in the funnel through the filter paper. 5) While the solution is being filtered, put more ammonia into the first jar to wash any remaining crystals into the funnel as soon as it drains. 6) Collect all the purplish crystals without touching the brown filter paper, and place them on the paper towels to dry for about an hour. Make sure that they are not too close to any lights or other sources of heat, as they could well detonate. While they are still wet, divide the wet material into about eight chunks. 7) After they dry, gently place the crystals onto a one square inch piece of duct tape. Cover it with a similar piece, and gently press the duct tape together around the crystal, making sure not to press the crystal itself. Finally, cut away most of the excess duct tape with a pair of scissors, and store the crystals in a cool dry safe place. They have a shelf life of about a week, and they should be stored in individual containers that can be thrown away, since they have a tendency to slowly decompose, a process which gives off iodine vapors, which will stain whatever they settle on. One possible way to increase their shelf life is to store them in airtight containers. To use them, simply throw them against any surface or place them where they will be stepped on or crushed. 3.12 MERCURY FULMINATE Mercury fulminate is perhaps one of the oldest known initiating compounds. It can be detonated by either heat or shock, which would make it of infinite value to a terrorist. Even the action of dropping a crystal of the fulminate causes it to explode. A person making this material would probably use the following procedure: MATERIALS EQUIPMENT _________ _________ mercury (5 g) glass stirring rod concentrated nitric 100 ml beaker (2) acid (35 ml) adjustable heat ethyl alcohol (30 ml) source distilled water blue litmus paper funnel and filter paper 1) In one beaker, mix 5 g of mercury with 35 ml of concentrated nitric acid, using the glass rod. 2) Slowly heat the mixture until the mercury is dissolved, which is when the solution turns green and boils. 3) Place 30 ml of ethyl alcohol into the second beaker, and slowly and carefully add all of the contents of the first beaker to it. Red and/or brown fumes should appear. These fumes are toxic and flammable. 4) After thirty to forty minutes, the fumes should turn white, indicating that the reaction is near completion. After ten more minutes, add 30 ml of the distilled water to the solution. 5) Carefully filter out the crystals of mercury fulminate from the liquid solution. Dispose of the solution in a safe place, as it is corrosive and toxic. 6) Wash the crystals several times in distilled water to remove as much excess acid as possible. Test the crystals with the litmus paper until they are neutral. This will be when the litmus paper stays blue when it touches the wet crystals 7) Allow the crystals to dry, and store them in a safe place, far away from any explosive or flammable material. This procedure can also be done by volume, if the available mercury cannot be weighed. Simply use 10 volumes of nitric acid and 10 volumes of ethanol to every one volume of mercury. 3.13 NITROGLYCERINE Nitroglycerine is one of the most sensitive explosives, if it is not the most sensitive. Although it is possible to make it safely, it is difficult. Many a young anarchist has been killed or seriously injured while trying to make the stuff. When Nobel's factories make it, many people were killed by the all-to-frequent factory explosions. Usually, as soon as it is made, it is converted into a safer substance, such as dynamite. An idiot who attempts to make nitroglycerine would use the following procedure: MATERIAL EQUIPMENT ________ _________ distilled water eye-dropper table salt 100 ml beaker sodium bicarbonate 200-300 ml beakers (2) concentrated nitric ice bath container acid (13 ml) ( a plastic bucket serves well ) concentrated sulfuric centigrade thermometer acid (39 ml) glycerine blue litmus paper 1) Place 150 ml of distilled water into one of the 200-300 ml beakers. 2) In the other 200-300 ml beaker, place 150 ml of distilled water and about a spoonful of sodium bicarbonate, and stir them until the sodium bicarbonate dissolves. Do not put so much sodium bicarbonate in the water so that some remains undissolved. 3) Create an ice bath by half filling the ice bath container with ice, and adding table salt. This will cause the ice to melt, lowering the overall temperature. 4) Place the 100 ml beaker into the ice bath, and pour the 13 ml of concentrated nitric acid into the 100 ml beaker. Be sure that the beaker will not spill into the ice bath, and that the ice bath will not overflow into the beaker when more materials are added to it. Be sure to have a large enough ice bath container to add more ice. Bring the temperature of the acid down to about 20 degrees centigrade or less. 5) When the nitric acid is as cold as stated above, slowly and carefully add the 39 ml of concentrated sulfuric acid to the nitric acid. Mix the two acids together, and cool the mixed acids to 10 degrees centigrade. It is a good idea to start another ice bath to do this. 6) With the eyedropper, slowly put the glycerine into the mixed acids, one drop at a time. Hold the thermometer along the top of the mixture where the mixed acids and glycerine meet. DO NOT ALLOW THE TEMPERATURE TO GET ABOVE 30 DEGREES CENTIGRADE; IF THE TEMPERATURE RISES ABOVE THIS TEMPERATURE, RUN LIKE HELL!!! The glycerine will start to nitrate immediately, and the temperature will immediately begin to rise. Add glycerine until there is a thin layer of glycerine on top of the mixed acids. It is always safest to make any explosive in small quantities. 7) Stir the mixed acids and glycerine for the first ten minutes of nitration, adding ice and salt to the ice bath to keep the temperature of the solution in the 100 ml beaker well below 30 degrees centigrade. Usually, the nitroglycerine will form on the top of the mixed acid solution, and the concentrated sulfuric acid will absorb the water produced by the reaction. 8) When the reaction is over, and when the nitroglycerine is well below 30 degrees centigrade, slowly and carefully pour the solution of nitroglycerine and mixed acid into the distilled water in the beaker in step 1. The nitroglycerine should settle to the bottom of the beaker, and the water-acid solution on top can be poured off and disposed of. Drain as much of the acid-water solution as possible without disturbing the nitroglycerine. 9) Carefully remove the nitroglycerine with a clean eye-dropper, and place it into the beaker in step 2. The sodium bicarbonate solution will eliminate much of the acid, which will make the nitroglycerine more stable, and less likely to explode for no reason, which it can do. Test the nitroglycerine with the litmus paper until the litmus stays blue. Repeat this step if necessary, and use new sodium bicarbonate solutions as in step 2. 10) When the nitroglycerine is as acid-free as possible, store it in a clean container in a safe place. The best place to store nitroglycerine is far away from anything living, or from anything of any value. Nitroglycerine can explode for no apparent reason, even if it is stored in a secure cool place. 3.14 PICRATES Although the procedure for the production of picric acid, or trinitrophenol has not yet been given, its salts are described first, since they are extremely sensitive, and detonate on impact. By mixing picric acid with metal hydroxides, such as sodium or potassium hydroxide, and evaporating the water, metal picrates can be formed. Simply obtain picric acid, or produce it, and mix it with a solution of (preferably) potassium hydroxide, of a mid range molarity. (about 6-9 M) This material, potassium picrate, is impact-sensitive, and can be used as an initiator for any type of high explosive. 3.2 LOW-ORDER EXPLOSIVES There are many low-order explosives that can be purchased in stores and used in explosive devices. However, it is possible that a wise gun store owner would not sell these substances to a suspicious-looking individual. Such an individual would then be forced to resort to making his own low-order explosives. 3.21 BLACK POWDER First made by the Chinese for use in fireworks, black powder was first used in weapons and explosives in the 12th century. It is very simple to make, but it is not very powerful or safe. Only about 50% of black powder is converted to hot gasses when it is burned; the other half is mostly very fine burned particles. Black powder has one major problem: it can be ignited by static electricity. This is very bad, and it means that the material must be made with wooden or clay tools. Anyway, a misguided individual could manufacture black powder at home with the following procedure: MATERIALS EQUIPMENT _________ _________ potassium clay grinding bowl nitrate (75 g) and clay grinder or or sodium wooden salad bowl nitrate (75 g) and wooden spoon sulfur (10 g) plastic bags (3) charcoal (15 g) 300-500 ml beaker (1) distilled water coffee pot or heat source 1) Place a small amount of the potassium or sodium nitrate in the grinding bowl and grind it to a very fine powder. Do this to all of the potassium or sodium nitrate, and store the ground powder in one of the plastic bags. 2) Do the same thing to the sulfur and charcoal, storing each chemical in a separate plastic bag. 3) Place all of the finely ground potassium or sodium nitrate in the beaker, and add just enough boiling water to the chemical to get it all wet. 4) Add the contents of the other plastic bags to the wet potassium or sodium nitrate, and mix them well for several minutes. Do this until there is no more visible sulfur or charcoal, or until the mixture is universally black. 5) On a warm sunny day, put the beaker outside in the direct sunlight. Sunlight is really the best way to dry black powder, since it is never too hot, but it is hot enough to evaporate the water. 6) Scrape the black powder out of the beaker, and store it in a safe container. Plastic is really the safest container, followed by paper. Never store black powder in a plastic bag, since plastic bags are prone to generate static electricity. 3.22 NITROCELLULOSE Nitrocellulose is usually called "gunpowder" or "guncotton". It is more stable than black powder, and it produces a much greater volume of hot gas. It also burns much faster than black powder when it is in a confined space. Finally, nitrocellulose is fairly easy to make, as outlined by the following procedure: MATERIALS EQUIPMENT _________ _________ cotton (cellulose) two (2) 200-300 ml beakers concentrated funnel and filter paper nitric acid blue litmus paper concentrated sulfuric acid distilled water 1) Pour 10 cc of concentrated sulfuric acid into the beaker. Add to this 10 cc of concentrated nitric acid. 2) Immediately add 0.5 gm of cotton, and allow it to soak for exactly 3 minutes. 3) Remove the nitrocottmNX and`��-��+�J-��+� ��+�z��"�--�__��-�+5� to wash it in. 4) Allow the material to dry, and then re-wash it. 5) After the cotton is neutral when tested with litmus paper, it is ready to be dried and stored. 3.23 FUEL-OXODIZER MIXTURES There are nearly an infinite number of fuel-oxodizer mixtures that can be produced by a misguided individual in his own home. Some are very effective and dangerous, while others are safer and less effective. A list of working fuel-oxodizer mixtures will be presented, but the exact measurements of each compound are debatable for maximum effectiveness. A rough estimate will be given of the percentages of each fuel and oxodizer: oxodizer, % by weight fuel, % by weight speed # notes ________________________________________________________________________________ potassium chlorate 67% sulfur 33% 5 friction/ impact sensitive rather unstable ________________________________________________________________________________ potassium chlorate 50% sugar 35% 5 fairly slow charcoal 15% burning; unstable ________________________________________________________________________________ potassium chlorate 50% sulfur 25% 8 extremely magnesium or unstable! aluminum dust 25% ________________________________________________________________________________ potassium chlorate 67% magnesium or 8 unstable aluminum dust 33% ________________________________________________________________________________ sodium nitrate 65% magnesium dust 30% ? unpredictable sulfur 5% burn rate ________________________________________________________________________________ potassium permanganate 60% glycerine 40% 4 delay before ignition depends WARNING: IGNITES SPONTANEOUSLY WITH GLYCERINE!!! upon grain size ________________________________________________________________________________ potassium permanganate 67% sulfur 33% 5 unstable ________________________________________________________________________________ potassium permangenate 60% sulfur 20% 5 unstable magnesium or aluminum dust 20% ________________________________________________________________________________ potassium permanganate 50% sugar 50% 3 ? ________________________________________________________________________________ potassium nitrate 75% charcoal 15% 7 this is sulfur 10% black powder! ________________________________________________________________________________ potassium nitrate 60% powdered iron 1 burns very hot or magnesium 40% ________________________________________________________________________________ potassium chlorate 75% phosphorus 8 used to make sesquisulfide 25% strike-anywhere matches ________________________________________________________________________________ ammonium perchlorate 70% aluminum dust 30% 6 solid fuel for + small amount of space shuttle iron oxide ________________________________________________________________________________ potassium perchlorate 67% magnesium or 10 flash powder (sodium perchlorate) aluminum dust 33% ________________________________________________________________________________ potassium perchlorate 60% magnesium or 8 alternate (sodium perchlorate) aluminum dust 20% flash powder sulfur 20% ________________________________________________________________________________ barium nitrate 30% aluminum dust 30% 9 alternate potassium perchlorate 30% flash powder ________________________________________________________________________________ barium peroxide 90% magnesium dust 5% 10 alternate aluminum dust 5% flash powder ________________________________________________________________________________ potassium perchlorate 50% sulfur 25% 8 slightly magnesium or unstable aluminum dust 25% ________________________________________________________________________________ potassium chlorate 67% red phosphorus 27% 7 very calcium carbonate 3% sulfur 3% unstable! impact sensitive ________________________________________________________________________________ potassium permanganate 50% powdered sugar 25% 7 unstable; aluminum or ignites if magnesium dust 25% it gets wet! ________________________________________________________________________________ potassium chlorate 75% charcoal dust 15% 6 unstable sulfur 10% ________________________________________________________________________________ NOTE: Mixtures that uses substitutions of sodium perchlorate for potassium perchlorate become moisture-absorbent and less stable. The higher the speed number, the faster the fuel-oxodizer mixture burns AFTER ignition. Also, as a rule, the finer the powder, the faster the rate of burning. As one can easily see, there is a wide variety of fuel-oxodizer mixtures that can be made at home. By altering the amounts of fuel and oxodizer(s), different burn rates can be achieved, but this also can change the sensitivity of the mixture. 3.24 PERCHLORATES As a rule, any oxidizable material that is treated with perchloric acid will become a low order explosive. Metals, however, such as potassium or sodium, become excellent bases for flash-type powders. Some materials that can be perchlorated are cotton, paper, and sawdust. To produce potassium or sodium perchlorate, simply acquire the hydroxide of that metal, e.g. sodium or potassium hydroxide. It is a good idea to test the material to be perchlorated with a very small amount of acid, since some of the materials tend to react explosively when contacted by the acid. Solutions of sodium or potassium hydroxide are ideal. 3.3 HIGH-ORDER EXPLOSIVES High order explosives can be made in the home without too much difficulty. The main problem is acquiring the nitric acid to produce the high explosive. Most high explosives detonate because their molecular structure is made up of some fuel and usually three or more NO2 ( nitrogen dioxide ) molecules. T.N.T., or Tri-Nitro-Toluene is an excellent example of such a material. When a shock wave passes through an molecule of T.N.T., the nitrogen dioxide bond is broken, and the oxygen combines with the fuel, all in a matter of microseconds. This accounts for the great power of nitrogen-based explosives. Remembering that these procedures are NEVER TO BE CARRIED OUT, several methods of manufacturing high-order explosives in the home are listed. 3.31 R.D.X. R.D.X., also called cyclonite, or composition C-1 (when mixed with plasticisers) is one of the most valuable of all military explosives. This is because it has more than 150% of the power of T.N.T., and is much easier to detonate. It should not be used alone, since it can be set off by a not-too severe shock. It is less sensitive than mercury fulminate, or nitroglycerine, but it is still too sensitive to be used alone. R.D.X. can be made by the surprisingly simple method outlined hereafter. It is much easier to make in the home than all other high explosives, with the possible exception of ammonium nitrate. MATERIALS EQUIPMENT _________ _________ hexamine 500 ml beaker or methenamine glass stirring rod fuel tablets (50 g) funnel and filter paper concentrated nitric acid (550 ml) ice bath container (plastic bucket) distilled water centigrade thermometer table salt blue litmus paper ice ammonium nitrate 1) Place the beaker in the ice bath, (see section 3.13, steps 3-4) and carefully pour 550 ml of concentrated nitric acid into the beaker. 2) When the acid has cooled to below 20 degrees centigrade, add small amounts of the crushed fuel tablets to the beaker. The temperature will rise, and it must be kept below 30 degrees centigrade, or dire consequences could result. Stir the mixture. 3) Drop the temperature below zero degrees centigrade, either by adding more ice and salt to the old ice bath, or by creating a new ice bath. Or, ammonium nitrate could be added to the old ice bath, since it becomes cold when it is put in water. Continue stirring the mixture, keeping the temperature below zero degrees centigrade for at least twenty minutes 4) Pour the mixture into a litre of crushed ice. Shake and stir the mixture, and allow it to melt. Once it has melted, filter out the crystals, and dispose of the corrosive liquid. 5) Place the crystals into one half a litre of boiling distilled water. Filter the crystals, and test them with the blue litmus paper. Repeat steps 4 and 5 until the litmus paper remains blue. This will make the crystals more stable and safe. 6) Store the crystals wet until ready for use. Allow them to dry completely using them. R.D.X. is not stable enough to use alone as an explosive. 7) Composition C-1 can be made by mixing 88.3% R.D.X. (by weight) with 11.1% mineral oil, and 0.6% lecithin. Kneed these material together in a plastic bag. This is a good way to desensitize the explosive. 8) H.M.X. is a mixture of T.N.T. and R.D.X.; the ratio is 50/50, by weight. it is not as sensitive, and is almost as powerful as straight R.D.X. 9) By adding ammonium nitrate to the crystals of R.D.X. after step 5, it should be possible to desensitize the R.D.X., and increase its power, since ammonium nitrate is very insensitive and powerful. Soduim or potassium nitrate could also be added; a small quantity is sufficient to stabilize the R.D.X. 10) R.D.X. detonates at a rate of 8550 meters/second when it is compressed to a density of 1.55 g/cubic cm. 3.32 AMMONIUM NITRATE Ammonium nitrate could be made by a terrorist according to the hap- hazard method in section 2.33, or it could be stolen from a construction site, since it is usually used in blasting, because it is very stable and insensitive to shock and heat. A terrorist could also buy several Instant Cold-Paks from a drug store or medical supply store. The major disadvantage with ammonium nitrate, from a terrorist's point of view, would be detonating it. A rather powerful priming charge must be used, and usually with a booster charge. The diagram below will explain. _________________________________________ | | | ________| | | | | T.N.T.| ammonium nitrate | |primer |booster| | |_______| | | | | | |_______|_______________________________| The primer explodes, detonating the T.N.T., which detonates, sending a tremendous shockwave through the ammonium nitrate, detonating it. 3.33 ANFOS ANFO is an acronym for Ammonium Nitrate - Fuel Oil Solution. An ANFO solves the only other major problem with ammonium nitrate: its tendency to pick up water vapor from the air. This results in the explosive failing to detonate when such an attempt is made. This is rectified by mixing 94% (by weight) ammonium nitrate with 6% fuel oil, or kerosene. The kerosene keeps the ammonium nitrate from absorbing moisture from the air. An ANFO also requires a large shockwave to set it off. 3.34 T.N.T. T.N.T., or Tri-Nitro-Toluene, is perhaps the second oldest known high explosive. Dynamite, of course, was the first. It is certainly the best known high explosive, since it has been popularized by early morning cartoons. It is the standard for comparing other explosives to, since it is the most well known. In industry, a T.N.T. is made by a three step nitration process that is designed to conserve the nitric and sulfuric acids which are used to make the product. A terrorist, however, would probably opt for the less economical one-step method. The one step process is performed by treating toluene with very strong (fuming) sulfuric acid. Then, the sulfated toluene is treated with very strong (fuming) nitric acid in an ice bath. Cold water is added the solution, and it is filtered. 3.35 POTASSIUM CHLORATE Potassium chlorate itself cannot be made in the home, but it can be obtained from labs. If potassium chlorate is mixed with a small amount of vaseline, or other petroleum jelly, and a shockwave is passed through it, the material will detonate with slightly more power than black powder. It must, however, be confined to detonate it in this manner. The procedure for making such an explosive is outlined below: MATERIALS EQUIPMENT _________ _________ potassium chlorate zip-lock plastic bag (9 parts, by volume) petroleum jelly clay grinding bowl (vaseline) or (1 part, by volume) wooden bowl and wooden spoon 1) Grind the potassium chlorate in the grinding bowl carefully and slowly, until the potassium chlorate is a very fine powder. The finer that it is powdered, the faster (better) it will detonate. 2) Place the powder into the plastic bag. Put the petroleum jelly into the plastic bag, getting as little on the sides of the bag as possible, i.e. put the vaseline on the potassium chlorate powder. 3) Close the bag, and kneed the materials together until none of the potassium chlorate is dry powder that does not stick to the main glob. If necessary, add a bit more petroleum jelly to the bag. 4) The material must me used within 24 hours, or the mixture will react to greatly reduce the effectiveness of the explosive. This reaction, however, is harmless, and releases no heat or dangerous products. 3.36 DYNAMITE The name dynamite comes from the Greek word "dynamis", meaning power. Dynamite was invented by Nobel shortly after he made nitroglycerine. It was made because nitroglycerine was so dangerously sensitive to shock. A misguided individual with some sanity would, after making nitroglycerine (an insane act) would immediately convert it to dynamite. This can be done by adding various materials to the nitroglycerine, such as sawdust. The sawdust holds a large weight of nitroglycerine per volume. Other materials, such as ammonium nitrate could be added, and they would tend to desensitize the explosive, and increase the power. But even these nitroglycerine compounds are not really safe. 3.37 NITROSTARCH EXPLOSIVES Nitrostarch explosives are simple to make, and are fairly powerful. All that need be done is treat various starches with a mixture of concentrated nitric and sulfuric acids. 10 ml of concentrated sulfuric acid is added to 10 ml of concentrated nitric acid. To this mixture is added 0.5 grams of starch. Cold water is added, and the apparently unchanged nitrostarch is filtered out. Nitrostarch explosives are of slightly lower power than T.N.T., but they are more readily detonated. 3.38 PICRIC ACID Picric acid, also known as Tri-Nitro-Phenol, or T.N.P., is a military explosive that is most often used as a booster charge to set off another less sensitive explosive, such as T.N.T. It another explosive that is fairly simple to make, assuming that one can acquire the concentrated sulfuric and nitric acids. Its procedure for manufacture is given in many college chemistry lab manuals, and is easy to follow. The main problem with picric acid is its tendency to form dangerously sensitive and unstable picrate salts, such as potassium picrate. For this reason, it is usually made into a safer form, such as ammonium picrate, also called explosive D. A social deviant would probably use a formula similar to the one presented here to make picric acid. MATERIALS EQUIPMENT _________ _________ phenol (9.5 g) 500 ml flask concentrated adjustable heat source sulfuric acid (12.5 ml) 1000 ml beaker concentrated nitric or other container acid (38 ml) suitable for boiling in distilled water filter paper and funnel glass stirring rod 1) Place 9.5 grams of phenol into the 500 ml flask, and carefully add 12.5 ml of concentrated sulfuric acid and stir the mixture. 2) Put 400 ml of tap water into the 1000 ml beaker or boiling container and bring the water to a gentle boil. 3) After warming the 500 ml flask under hot tap water, place it in the boiling water, and continue to stir the mixture of phenol and acid for about thirty minutes. After thirty minutes, take the flask out, and allow it to cool for about five minutes. 4) Pour out the boiling water used above, and after allowing the container to cool, use it to create an ice bath, similar to the one used in section 3.13, steps 3-4. Place the 500 ml flask with the mixed acid an phenol in the ice bath. Add 38 ml of concentrated nitric acid in small amounts, stirring the mixture constantly. A vigorous but "harmless" reaction should occur. When the mixture stops reacting vigorously, take the flask out of the ice bath. 5) Warm the ice bath container, if it is glass, and then begin boiling more tap water. Place the flask containing the mixture in the boiling water, and heat it in the boiling water for 1.5 to 2 hours. 6) Add 100 ml of cold distilled water to the solution, and chill it in an ice bath until it is cold. 7) Filter out the yellowish-white picric acid crystals by pouring the solution through the filter paper in the funnel. Collect the liquid and dispose of it in a safe place, since it is corrosive. 8) Wash out the 500 ml flask with distilled water, and put the contents of the filter paper in the flask. Add 300 ml of water, and shake vigorously. 9) Re-filter the crystals, and allow them to dry. 10) Store the crystals in a safe place in a glass container, since they will react with metal containers to produce picrates that could explode spontaneously. 3.39 AMMONIUM PICRATE Ammonium picrate, also called Explosive D, is another safety explosive. It requires a substantial shock to cause it to detonate, slightly less than that required to detonate ammonium nitrate. It is much safer than picric acid, since it has little tendency to form hazardous unstable salts when placed in metal containers. It is simple to make from picric acid and clear household ammonia. All that need be done is put the picric acid crystals into a glass container and dissolve them in a great quantity of hot water. Add clear household ammonia in excess, and allow the excess ammonia to evaporate. The powder remaining should be ammonium picrate. 3.40 NITROGEN TRICHLORIDE Nitrogen trichloride, also known as chloride of azode, is an oily yellow liquid. It explodes violently when it is heated above 60 degrees celsius, or when it comes in contact with an open flame or spark. It is fairly simple to produce. 1) In a beaker, dissolve about 5 teaspoons of ammonium nitrate in water. Do not put so much ammonium nitrate into the solution that some of it remains undissolved in the bottom of the beaker. 2) Collect a quantity of chlorine gas in a second beaker by mixing hydrochloric acid with potassium permanganate in a large flask with a stopper and glass pipe. 3) Place the beaker containing the chlorine gas upside down on top of the beaker containing the ammonium nitrate solution, and tape the beakers together. Gently heat the bottom beaker. When this is done, oily yellow droplets will begin to form on the surface of the solution, and sink down to the bottom. At this time, remove the heat source immediately. Alternately, the chlorine can be bubbled through the ammonium nitrate solution, rather than collecting the gas in a beaker, but this requires timing and a stand to hold the beaker and test tube. The chlorine gas can also be mixed with anhydrous ammonia gas, by gently heating a flask filled with clear household ammonia. Place the glass tubes from the chlorine-generating flask and the tube from the ammonia-generating flask in another flask that contains water. 4) Collect the yellow droplets with an eyedropper, and use them immediately, since nitrogen trichloride decomposes in 24 hours. 3.41 LEAD AZIDE Lead Azide is a material that is often used as a booster charge for other explosive, but it does well enough on its own as a fairly sensitive explosive. It does not detonate too easily by percussion or impact, but it is easily detonated by heat from an igniter wire, or a blasting cap. It is simple to produce, assuming that the necessary chemicals can be procured. By dissolving sodium azide and lead acetate in water in separate beakers, the two materials are put into an aqueous state. Mix the two beakers together, and apply a gentle heat. Add an excess of the lead acetate solution, until no reaction occurs, and the precipitate on the bottom of the beaker stops forming. Filter off the solution, and wash the precipitate in hot water. The precipitate is lead azide, and it must be stored wet for safety. If lead acetate cannot be found, simply acquire acetic acid, and put lead metal in it. Black powder bullets work well for this purpose. 3.5 OTHER "EXPLOSIVES" The remaining section covers the other types of materials that can be used to destroy property by fire. Although none of the materials presented here are explosives, they still produce explosive-style results. 3.51 THERMIT Thermit is a fuel-oxodizer mixture that is used to generate tremendous amounts of heat. It was not presented in section 3.23 because it does not react nearly as readily. It is a mixture of iron oxide and aluminum, both finely powdered. When it is ignited, the aluminum burns, and extracts the oxygen from the iron oxide. This is really two very exothermic reactions that produce a combined temperature of about 2200 degrees C. This is half the heat produced by an atomic weapon. It is difficult to ignite, however, but when it is ignited, it is one of the most effective firestarters around. MATERIALS _________ powdered aluminum (10 g) powdered iron oxide (10 g) 1) There is no special procedure or equipment required to make thermit. Simply mix the two powders together, and try to make the mixture as homogenous as possible. The ratio of iron oxide to aluminum is 50% / 50% by weight, and be made in greater or lesser amounts. 2) Ignition of thermite can be accomplished by adding a small amount of potassium chlorate to the thermit, and pouring a few drops of sulfuric acid on it. This method and others will be discussed later in section 4.33. The other method of igniting thermit is with a magnesium strip. Finally, by using common sparkler-type fireworks placed in the thermit, the mixture can be ignited. 3.52 MOLOTOV COCKTAILS First used by Russians against German tanks, the Molotov cocktail is now exclusively used by terrorists worldwide. They are extremely simple to make, and can produce devastating results. By taking any highly flammable material, such as gasoline, diesel fuel, kerosene, ethyl or methyl alcohol, lighter fluid, turpentine, or any mixture of the above, and putting it into a large glass bottle, anyone can make an effective firebomb. After putting the flammable liquid in the bottle, simply put a piece of cloth that is soaked in the liquid in the top of the bottle so that it fits tightly. Then, wrap some of the cloth around the neck and tie it, but be sure to leave a few inches of lose cloth to light. Light the exposed cloth, and throw the bottle. If the burning cloth does not go out, and if the bottle breaks on impact, the contents of the bottle will spatter over a large area near the site of impact, and burst into flame. Flammable mixtures such as kerosene and motor oil should be mixed with a more volatile and flammable liquid, such as gasoline, to insure ignition. A mixture such as tar or grease and gasoline will stick to the surface that it strikes, and burn hotter, and be more difficult to extinguish. A mixture such as this must be shaken well before it is lit and thrown 3.53 CHEMICAL FIRE BOTTLE The chemical fire bottle is really an advanced molotov cocktail. Rather than using the burning cloth to ignite the flammable liquid, which has at best a fair chance of igniting the liquid, the chemical fire bottle utilizes the very hot and violent reaction between sulfuric acid and potassium chlorate. When the container breaks, the sulfuric acid in the mixture of gasoline sprays onto the paper soaked in potassium chlorate and sugar. The paper, when struck by the acid, instantly bursts into a white flame, igniting the gasoline. The chance of failure to ignite the gasoline is less than 2%, and can be reduced to 0%, if there is enough potassium chlorate and sugar to spare. MATERIALS EQUIPMENT _________ _________ potassium chlorate glass bottle (2 teaspoons) (12 oz.) sugar (2 teaspoons) cap for bottle, with plastic inside concentrated cooking pan with raised sulfuric acid (4 oz.) edges gasoline (8 oz.) paper towels glass or plastic cup and spoon 1) Test the cap of the bottle with a few drops of sulfuric acid to make sure that the acid will not eat away the bottle cap during storage. If the acid eats through it in 24 hours, a new top must be found and tested, until a cap that the acid does not eat through is found. A glass top is excellent. 2) Carefully pour 8 oz. of gasoline into the glass bottle. 3) Carefully pour 4 oz. of concentrated sulfuric acid into the glass bottle. Wipe up any spills of acid on the sides of the bottle, and screw the cap on the bottle. Wash the bottle's outside with plenty of water. Set it aside to dry. 4) Put about two teaspoons of potassium chlorate and about two teaspoons of sugar into the glass or plastic cup. Add about 1/2 cup of boiling water, or enough to dissolve all of the potassium chlorate and sugar. 5) Place a sheet of paper towel in the cooking pan with raised edges. Fold the paper towel in half, and pour the solution of dissolved potassium chlorate and sugar on it until it is thoroughly wet. Allow the towel to dry. 6) When it is dry, put some glue on the outside of the glass bottle containing the gasoline and sulfuric acid mixture. Wrap the paper towel around the bottle, making sure that it sticks to it in all places. Store the bottle in a place where it will not be broken or tipped over. 7) When finished, the solution in the bottle should appear as two distinct liquids, a dark brownish-red solution on the bottom, and a clear solution on top. The two solutions will not mix. To use the chemical fire bottle, simply throw it at any hard surface. 8) NEVER OPEN THE BOTTLE, SINCE SOME SULFURIC ACID MIGHT BE ON THE CAP, WHICH COULD TRICKLE DOWN THE SIDE OF THE BOTTLE AND IGNITE THE POTASSIUM CHLORATE, CAUSING A FIRE AND/OR EXPLOSION. 9) To test the device, tear a small piece of the paper towel off the bottle, and put a few drops of sulfuric acid on it. The paper towel should immediately burst into a white flame. 3.54 BOTTLED GAS EXPLOSIVES Bottled gas, such as butane for refilling lighters, propane for propane stoves or for bunsen burners, can be used to produce a powerful explosion. To make such a device, all that a simple-minded anarchist would have to do would be to take his container of bottled gas and place it above a can of Sterno or other gelatinized fuel, and light the fuel and run. Depending on the fuel used, and on the thickness of the fuel container, the liquid gas will boil and expand to the point of bursting the container in about five minutes. In theory, the gas would immediately be ignited by the burning gelatinized fuel, producing a large fireball and explosion. Unfortunately, the bursting of the bottled gas container often puts out the fuel, thus preventing the expanding gas from igniting. By using a metal bucket half filled with gasoline, however, the chances of ignition are better, since the gasoline is less likely to be extinguished. Placing the canister of bottled gas on a bed of burning charcoal soaked in gasoline would probably be the most effective way of securing ignition of the expanding gas, since although the bursting of the gas container may blow out the flame of the gasoline, the burning charcoal should immediately re-ignite it. Nitrous oxide, hydrogen, propane, acetylene, or any other flammable gas will do nicely.